%0 Journal Article
%T <br>
%A 刘莹莹
%A 杨进
%A 韩雪
%A 马建方
%J 物理化学学报
%D 2018
%R 10.3866/PKU.WHXB201709151
%X 利用四[1-(1, 2, 4-三氮唑基)甲基]间苯二酚杯[4]芳烃配体(TTR4A)在溶剂热的条件下合成了两个配位聚合物，[[Zn2(TTR4A)(L)2]·DMF·4H2O]n(化合物1) (DMF = N, N-二甲基甲酰胺)和[[Co(TTR4A)Cl2]·DMA·H2O]n (化合物2) (H2L = 4, 4’-联苯二甲酸) (DMA = N, N-二甲基乙酰胺)。通过单晶X射线衍射方法对这两个配位聚合物的结构进行了确定。利用红外、元素分析、粉末X射线衍射(PXRD)和热重表征手段对化合物1和2进行了表征。在化合物1中，四个L配体连接着四个Zn(Ⅱ)离子形成了环状的Zn4L4结构单元，该结构单元进一步地被TTR4A链接形成了一维链状结构。在化合物2中，TTR4A的四个三氮唑基团各连接一个Co(Ⅱ)离子形成二维层状结构。此外，我们对化合物1的荧光性能进行了研究，荧光测定表明固态条件下化合物1发出很强的荧光，并能够选择性地对Fe3+、Cr2O72？和硝基苯分子产生响应。<br>Two new coordination polymers, namely, [[Zn2(TTR4A)(L)2]·DMF·4H2O]n (compound 1) and [[Co(TTR4A)Cl2]·DMA·H2O]n (compound 2), have been synthesized under solvothermal conditions (TTR4A = tetrakis(1, 2, 4-triazol-ylmethylresorcin[4]arene), L = 4, 4'-biphenyldicarboxylic acid, DMF = N, N-dimethylformamide and DMA = N, N-dimethylacetamide). Crystal structures of the coordination compounds 1 and 2 were determined by single-crystal X-ray diffraction analyses, and further characterized by infrared spectra, elemental analyses, powder X-ray diffraction, and thermogravimetric analyses. In coordination compound 1, four L ligands bridge four adjacent Zn(Ⅱ) atoms to generate macrocyclic Zn4L4 units, which are further linked by the TTR4A ligands into a one-dimensional chain structure. In coordination compound 2, four 1, 2, 4-triazole groups of each TTR4A ligand bridge four Co(Ⅱ) atoms to form a two-dimensional layer structure. Furthermore, studies on the luminescent properties of compound 1 in solid state at room temperature reveal that it exhibits an intense emission peak. Luminescent-sensing detections for Fe3+, Cr2O72？, and nitrobenzene solvents were also investigated by using compound 1 as the potential luminescent sensor
%U http://www.whxb.pku.edu.cn/CN/Y2018/V34/I5/476