%0 Journal Article
%T 具有开放骨架双核锌羧酸配合物的设计合成与结构表征&lt;br&gt;Construction and Characterization of an Open-Framework Binuclear Zinc Carboxylate
%A 李会端
%J 西南大学学报(自然科学版)
%D 2017
%R 10.13718/j.cnki.xdzk.2017.11.015
%X 选择含氮的有机羧酸配体1，3-di(3'，5'-dicarboxylphenyl)pyridine(C&lt;sub&gt;21&lt;/sub&gt;H&lt;sub&gt;13&lt;/sub&gt;NO&lt;sub&gt;8&lt;/sub&gt;，H&lt;sub&gt;4&lt;/sub&gt;L)，与过渡金属锌在DMA/CH&lt;sub&gt;3&lt;/sub&gt;CN/H&lt;sub&gt;2&lt;/sub&gt;O的混合溶剂热体系中配位组装，合成了一例具有3D开放骨架结构的双核锌金属羧酸配位化合物——Zn&lt;sub&gt;2&lt;/sub&gt;(C&lt;sub&gt;21&lt;/sub&gt;H&lt;sub&gt;9&lt;/sub&gt;NO&lt;sub&gt;8&lt;/sub&gt;)(H&lt;sub&gt;2&lt;/sub&gt;O) (配合物1).用单晶X-射线衍射分析确定了其晶体学结构，配合物1结晶在正交晶系，P2&lt;sub&gt;1&lt;/sub&gt;2&lt;sub&gt;1&lt;/sub&gt;2&lt;sub&gt;1&lt;/sub&gt;空间群(No.19)；有机羧酸衍生物配体H&lt;sub&gt;4&lt;/sub&gt;L结构中的羧酸氧原子与金属锌螯合配位形成1个双核锌的次级结构单元，再通过有机配体的配位作用连接形成配合物1的三维开放骨架结构，沿y轴方向具有空旷的孔道结构.&lt;br&gt;The construction, crystal structure and properties of multinuclear metal carboxylate frameworks and their potential applications have attracted considerable attention worldwide. In this study, a novel open-framework binuclear zinc carboxylate, Zn&lt;sub&gt;2&lt;/sub&gt;(C&lt;sub&gt;21&lt;/sub&gt;H&lt;sub&gt;9&lt;/sub&gt;NO&lt;sub&gt;8&lt;/sub&gt;)(H&lt;sub&gt;2&lt;/sub&gt;O) (compound 1), was constructed from 1, 3-di(3', 5'-dicarboxylphenyl)pyridine (H&lt;sub&gt;4&lt;/sub&gt;L) with the transition metal zinc under DMA/CH&lt;sub&gt;3&lt;/sub&gt;CN/H&lt;sub&gt;2&lt;/sub&gt;O mixed solvothermal conditions. Single-crystal X-ray diffraction analysis revealed that compound 1 crystallized in the orthorhombic space group P2&lt;sub&gt;1&lt;/sub&gt;2&lt;sub&gt;1&lt;/sub&gt;2&lt;sub&gt;1&lt;/sub&gt; (No.19). The oxygen atoms in carboxylate chelated with Zn to form a secondary building unit (SBU) featuring binuclear zinc, and these SBUs were constructed by H&lt;sub&gt;4&lt;/sub&gt;L further into the open-frameworks of compound 1 featuring extra-large channels along y axis
%K 有机羧酸配体
%K 溶剂热合成
%K 双核锌羧酸配合物
%K 超大孔道&lt
%K br&gt
%K organic carboxylate
%K solvothermal synthesis
%K binuclear zinc carboxylate frameworks
%K extra-large channel
%U http://xbgjxt.swu.edu.cn/jsuns/html/jsuns/2017/11/201711015.htm