%0 Journal Article
%T Ag(Ⅰ)催化的分子内氢胺化-Michael加成串联反应
%A 吴佩煜
%A 韩志勇
%J 中国科学技术大学学报
%D 2016
%R 10.3969/j.issn.0253-2778.2016.10.003
%X 通过甘氨酸酯衍生的炔胺化合物在Ag(Ⅰ)催化下发生分子内氢胺化-Michael加成串联反应，在较为温和的条件下合成了多取代的3,4-二氢吡咯结构.该方法为合成多取代的3,4-二氢吡咯结构提供了一种高效简便的途径.</br>Abstract：Starting from amino alkynes derived from glycine esters, silver(Ⅰ) catalyst was employed for a tandem intramolecular hydroamination/Michael addition process under mild conditions. This reaction provides an efficient approach to substituted 3,4-dihydro-2H-pyrroles
%K 串联反应
%K 氢胺化
%K 银催化
%K Michael加成
%K 3
%K 4-二氢吡咯&lt
%K /br&gt
%K Key words： cascade reaction hydroamination silver catalysis
%K Michael addition 3
%K 4-dihydro-2H-pyrroles
%U http://just.ustc.edu.cn/CN/abstract/abstract227.shtml