%0 Journal Article %T Unique Pulsed-Laser Deposition Production of Anatase and Rutile TiO<sub>2</sub> on Al<sub>2</sub>O<sub>3</sub> %A Alexandra Gordienko %A Anthony B. Kaye %J Crystal Structure Theory and Applications %P 19-31 %@ 2169-2505 %D 2018 %I Scientific Research Publishing %R 10.4236/csta.2018.72002 %X Two pure hexagonal phases of titanium dioxide, anatase and rutile, were grown on c-cut Al2O3 substrates via pulsed-laser deposition by changing only the growth and annealing conditions, but without changing the substrate, target, or working gas. Purity of each phase was confirmed by x-ray diffraction, the quality of each film was studied using atomic force microscopy and scanning electron microscopy, and the interface between each substrate and film was studied using x-ray photoelectron spectroscopy. A binding layer of Ti2O3 was found to explain anatase growth under the very large lattice mismatch conditions. %K Titania %K Anatase %K Rutile %K Sapphire %K PLD %U http://www.scirp.org/journal/PaperInformation.aspx?PaperID=87558