%0 Journal Article
%T Thermoplasticity in Polyurethane-Imide Elastomers
%A Tomohiro Ueda
%A Shin-Ichi Inoue
%J Open Journal of Polymer Chemistry
%P 11-20
%@ 2165-6711
%D 2018
%I Scientific Research Publishing
%R 10.4236/ojpchem.2018.81002
%X
Polyurethane-imide elastomers (PUIEs) are formed from isocyanates, polyols,
diamines, and acid anhydrides through liquid polymerization. However,
thermoplastic PUIEs have rarely been reported because the synthesis of thermoplastic
PUIEs remains a challenge in polymer chemistry. In this study,
PUIEs were prepared from 4,4'-diphenylmethane diisocyanate, polyols (polytetramethylene
glycol (Mw = 1000), polycaprolactone diol (Mw = 1000), and
polycarbonate diol (Mw = 1000)), 4,4'-oxydianiline, and acid anhydrides (pyromellitic
dianhydride and 4,4'-oxydiphtaric anhydride). The thermoplasticities
of the resultant PUIEs were investigated, and only PUIEs synthesized using
4,4'-oxydiphtaric anhydride expressed thermoplasticity.
%K Polyurethane-Imide Elastomer
%K Polyol
%K Acid Anhydride
%K Morphology
%K Chemical and Physical Properties
%U http://www.scirp.org/journal/PaperInformation.aspx?PaperID=82626