%0 Journal Article %T Thermoplasticity in Polyurethane-Imide Elastomers %A Tomohiro Ueda %A Shin-Ichi Inoue %J Open Journal of Polymer Chemistry %P 11-20 %@ 2165-6711 %D 2018 %I Scientific Research Publishing %R 10.4236/ojpchem.2018.81002 %X
Polyurethane-imide elastomers (PUIEs) are formed from isocyanates, polyols, diamines, and acid anhydrides through liquid polymerization. However, thermoplastic PUIEs have rarely been reported because the synthesis of thermoplastic PUIEs remains a challenge in polymer chemistry. In this study, PUIEs were prepared from 4,4'-diphenylmethane diisocyanate, polyols (polytetramethylene glycol (Mw = 1000), polycaprolactone diol (Mw = 1000), and polycarbonate diol (Mw = 1000)), 4,4'-oxydianiline, and acid anhydrides (pyromellitic dianhydride and 4,4'-oxydiphtaric anhydride). The thermoplasticities of the resultant PUIEs were investigated, and only PUIEs synthesized using 4,4'-oxydiphtaric anhydride expressed thermoplasticity.
%K Polyurethane-Imide Elastomer %K Polyol %K Acid Anhydride %K Morphology %K Chemical and Physical Properties %U http://www.scirp.org/journal/PaperInformation.aspx?PaperID=82626