%0 Journal Article
%T Dicyclopentamethylenethiuram Disulfide as Precursor of Mononuclear Complexes: Oxidative Cleavage of Metal-Metal Bond in [CpMo(CO)<sub>3</sub>]<sub>2</sub> and Molecular Structure of <i>cis</i>-[CpMo(CO)<sub>2</sub>{S<sub>2</sub>C-N(CH<sub>2</sub>)<sub>5</sub>}]
%A Md. Manzurul Karim
%A Shafikul Islam
%A Md. RafikulIslam
%A Mohammad R. Karim
%A Tasneem A. Siddiquee
%J Crystal Structure Theory and Applications
%P 67-72
%@ 2169-2505
%D 2017
%I Scientific Research Publishing
%R 10.4236/csta.2017.64006
%X The reaction of [CpMo(CO)3]2 with dicyclopentamethylenethiuram disulfide in refluxing xylene resulted a novel mono nuclear complex,
cis-[(CpMo(CO)2{S2C-N(CH2)5}] as red crystals in moderate yield. The compound was formed by the oxidative cleavage of metal-metal bond in [CpMo(CO)3]2 together with a reductive sulfur-sulfur bond scission in the ligand.
%K Dicyclopentamethylenethiuram Disulfide (Dcpmtd)
%K Oxidation Number
%K Oxida-tive Cleavage
%K Coordination Number
%K Mononuclear Complex
%K X-Ray Crystal Structure
%U http://www.scirp.org/journal/PaperInformation.aspx?PaperID=80749