%0 Journal Article
%T Structure of Aldoses Condensation Products with 2-Hydroxy- and 2-Aminobenzohydrazides
%A Igor V. Lagoda
%A Andrei Yu Ershov
%A Stanislav I. Yakimovich
%A Marina Yu Vasileva
%A Valery A. Polukeev
%A Ludmila Yu Kuleshova
%A Irina S. Korovina
%A Valery V. Shamanin
%J Open Access Library Journal
%V 3
%N 5
%P 1-6
%@ 2333-9721
%D 2016
%I Open Access Library
%R 10.4236/oalib.1102636
%X The structure of the condensation products of
2-hydroxybenzohydrazide, 2-aminobenzohydrazide, and N-methyl-N-(2-aminobenzo) hydrazide with a series of aldoses
(L-arabinose, D-ribose, L- rhamnose, D-galactose, D-glucose, and D-mannose) was
studied by <sup>1</sup>H- and <sup>13</sup>C-NMR spectroscopy. The condensation
products of aldoses with 2-hydroxybenzohydrazide and 2-aminobenzohydra- zide in
DMSO<i>d</i><sub>6</sub> solutions exist as
equilibrium mixtures of linear acylhydrazone and cyclic pyranose and furanose
forms. The aldoses condensation products with N-methyl-N-(2-aminobenzo)hy- drazide in the crystalline state and in DMSO<i>d</i><sub>6</sub> solutions have cyclic benzo-1,2,4-triazepin
structure.
%K Aldoses 2-Hydroxy- and 2-Aminobenzohydrazides
%K Benzo-1
%K 2
%K 4-Triazepines
%K Ring-Chain-Ring Tautomerism
%U http://www.oalib.com/paper/5266295