%0 Journal Article
%T synthesis,spectralandmagneticcharacterisationofsomebimetallicalkoxidesofnickel(ⅱ)withgallium(ⅲ)andzirconium(iv)
%A Mehrotra. R. C.？
%A Jain. Rama？
%A Rai. A. K.？
%J 无机化学学报
%P 96-107
%D 1987
%X someinterestingbimetallicisopropoxidesofnickel(ⅱ)withgallium(ⅲ)andzirconium(ⅳ),ni[ga(opr1)4]2andni[zr2(opr1)9]2havebeensynthesizedbytheinteractionofnicl2·2pr1ohwithk[ga(opr1)4],andk[zr2(opr1)9]respectively,in1:2molarratio.thesebimetallicisopropoxidesundergofacilealcoholinterchangereactionswithprimaryalcohols.however,reactionswithtertiaryalcoholsresultintheisolationofpartiallysubstitutedderivativeswiththecompositions,ni[ga(opr1)(obut)3]2andni[zr2(opr1)3(obut)6]2.characterisationofthesederivativeshasbeenmadeonthebasisofelementalanalyses,infrared,electronicspectralandmagneticsusceptibilitymeasurements.thesestudiessuggestanoctahedralgeometryfornickel(ⅱ)intheprimarybimetallicalkoxides,whileinthecaseofsecondaryandtertiaryderivatives,anequilibriumissuggestedbetweenoctahedralandtetrahedralforms.
%K bimetallic
%K alkoxide
%K nickel(ⅱ)
%K gallium(ⅲ)
%K zirconium(ⅳ)
%U http://www.wjhxxb.cn/wjhxxbcn/ch/reader/view_abstract.aspx?file_no=19870213&flag=1