%0 Journal Article %T transformationofchlorineinnacl-loadedvictorianbrowncoalduringthegasificationinsteam %A zhang %A shu %A mohammad %A asadullah %A rosalie %A hocking %A lin %A jian-ying %A li %A chun-zhu %J 燃料化学学报 %P 1409-1414 %D 2012 %X ?thisstudyistoexaminethechangesinclvolatilizationsandchemicalformsinnacl-loadedvictorianbrowncoalduringgasificationinsteamat800℃usingclk-edgex-rayabsorptionnear-edgestructure(xanes)spectroscopy.thecharsampleswerepreparedinanovelone-stagefluidised-bed/fixed-bedquartzreactoratafastheatingrate.thesampleswerethencollectedandsealedinanargon-filledbaginordertominimisepossibleoxidationofcharandclbyairpriortoanalysisbyxanes.char-steamreactionswerefoundtosignificantlyaffectthetransformationofcl,includingthepossibleformationofchlorine-containingorganicstructures.ontheotherhand,volatile-charinteractionsduringthegasificationappearedtoenhancetheclretentionandpreventtheformationoforganicchlorinecompoundsinchars. %K chlorine %K gasification %K volatile-charinteractions %K xanes %U http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract18076.shtml