%0 Journal Article
%T Pt(II) Complexes with Linear Diamines¡ªPart I: Vibrational Study of Pt-Diaminopropane
%A Ana L. M. Batista de Carvalho
%A S¨®nia M. Fiuza
%A John Tomkinson
%A Lu¨ªs A. E. Batista de Carvalho
%A M. Paula M. Marques
%J Spectroscopy: An International Journal
%D 2012
%I Hindawi Publishing Corporation
%R 10.1155/2012/206297
%X A conformational analysis of the Pt(dap)Cl2 complex (dap=1,3-diaminopropane) was performed by vibrational spectroscopy (FTIR, Raman, and INS), coupled to quantum mechanical methods within the density functional theory (DFT) and effective core potential (ECP) approaches. A complete spectral assignment of the system was achieved, due to the combined use of all available vibrational spectroscopic techniques. A good agreement was found between experimental and theoretical results, as well as with reported data for analogous complexes (e.g., cisplatin).
%U http://www.hindawi.com/journals/spectroscopy/2012/206297/