%0 Journal Article
%T Synthesis by Microwave Irradiation, Crystal Structure and Spectral Properties
%A LUOKaijun
%A JINGKai
%A XIEYun
%A XULingling
%A WANGJianwei
%J 四川师范大学学报(自然科学版)
%D 2010
%X Mononuclearplatinum(II)complexwith2phenylpyridineligands,(ppy)Pt(II)(Hppy)ClhasbeensynthesizedbythereactionofPt(IV)compound,H2PtCl6·6H2O,and2phenylpyridineundermicrowaveirradiation.Firstly,withrefluxduringmicrowaveirradiationfor15mininthe3∶1mixturesolventof2ethoxyethanolandwater,thePt(IV)compound,H2PtCl6·6H2Oreactswith2phenylpyridinetoformPt(IV)complexwiththestructureof(ppy)2Pt(IV)Cl2;then,(ppy)2Pt(IV)Cl2isreducedanddissociatedinthepresenceofexcesssodiumcarbonate(Na2CO3)aftermicrowaveirradiationfor5minintothefinaltitlecomplexwiththestructureof(ppy)Pt(II)(Hppy)Cl.ThetotalyieldbasedonH2PtCl6·6H2Ois62.1%.Thetitlecompoundhasbeencharacterizedby1HNMR,MSEISandsinglecrystalXraystructureanalysis.
%K mononuclearplatinum(II)complex
%K microwaveirradiation
%K crystalstructuredoi10.3969/j.issn.1001-8395.2010.06.020
%U http://jsnu.paperopen.com/oa/darticle.aspx?type=view&id=201006020