%0 Journal Article %T EnhancedFormationofHCFC141bHydratewithHCFC141b-in-waterEmulsion %A 周锡堂 %A 关进安 %A 梁德青 %J 过程工程学报 %D 2010 %X EnhancedformationofHCFC141bhydratewasstudiedwithHCFC141bemulsionbeforethehydrateformation.TergitolTMN6wasselectedasemulgator,HCFC141bandwaterwereintroducedintoanairtightemulsifieratthemolecularratioof171andemulsifiedatthetemperatureof14℃underthestirringspeedof4000~6400r/min.AndHCFC141bhydrateformedanddecomposedwiththechangeofprogrammedtemperature.TheexperimentalresultsshowedthatwiththenewmethodHCFC141bhydratebegantoforminthetimeof30min(inglycol-waterbath)or100min(inairbath)eveninstaticstate,andunderthesameconditionwithconventionalmethod(non-emulsion)thehydratecouldnotform,atleastitdifficultlyformed.AndindynamicstateHCFC141bemulsionformedhydratein20minearlierthanthemixedliquiddid,liquidfromhydratedecompositionwasemulsifiedafterbriefstirring,andformedhydrateagainmoreeasilythanthebrand-newemulsion. %K enhance %K HCFC141bhydrate %K emulsion %K formation %K decomposition %U http://www.jproeng.com/qikan/Cpaper/zhaiyao.asp?bsid=15357