%0 Journal Article
%T ApplicationofFilm-formingAdditivesforIonicLiquidBasedElectrolyte
%A 孙敏倩
%A 胡志强
%A 蔡迎军
%A 董陶
%A 吕兴梅
%J 过程工程学报
%D 2012
%X N-methyl-N-propylpiperidiniumbis(trifluoromethanesulfonyl)imidewassynthesizedfortheapplicationinionicliquidbasedelectrolytesinlithiumionbattery,10%vinylenecarbonate(VC)and10%1,3-propanesultone(PS)wereaddedtotheelectrolytesystemrespectivelyasadditivestoimprovethepropertyofsolidelectrolyteinterfaceandcyclicperformance.Theresultsofcyclicvoltammetryshowedthathomogenousandcompactsolidelectrolyteinterfacefilmformedongraphiteelectrodewhichwasdetectedbyobservingthemorphologyofcycledgraphiteanode.CharginganddischargingperformanceofLiFePO4/Lihalfcellwastestedintheelectrolytewithorwithoutadditives.Theinitialspecificdischargingcapacitieswereincreasedto129.4and123.0mA×h/gbytheadditionofVCandPS,respectively,comparedwiththatofadditive-freeelectrolyte.Thedischargingretentionswere88.9%and84.6%inelectrolytecontainingVCandPSafter10cycles.
%K vinylenecarbonate
%K 1
%K 3-propanesultone
%K N-methyl-N-propylpiperidiniumbis(trifluoromethanesulfonyl)imide
%K solidelectrolyteinterface
%U http://www.jproeng.com/qikan/Cpaper/zhaiyao.asp?bsid=16635