%0 Journal Article %T EffectofTetrachloroethyleneonSphaleriteLeaching %A 王兴尧 %A 彭鹏 %A 谢慧琴 %A 卢立柱 %J 过程工程学报 %D 2004 %X Theeffectsoftetrachloroethylene(C2Cl4)onsphaleriteleachinginFeCl3-HClwereinvestigatedinviewofsimultaneousmasstransferandreaction,andtheleachingmodelswithandwithoutorganicsolventC2Cl4werederived.TheleachingexperimentsandtheSEMresultsshowthatC2Cl4isaneffectiveorganicsolventforsphaleriteleachinginFeCl3-HClsystemtobeacceleratedandforthesulfurtobeseparated.AddingC2Cl4intheFeCl3-HClmediumwillturnthekineticmodelcontrolledbysulfurlayerdiffusionwithprocessactivationenergyof67.9kJ/molintomixeddiffusionwiththeenergyreducedto55.1kJ/molwhen20mlofC2Cl4wasadded. %K sphaleriteleaching %K sulfurlayer %K tetrachloroethylene %K kineticmodel %U http://www.jproeng.com/qikan/Cpaper/zhaiyao.asp?bsid=667