%0 Journal Article
%T Ni(II),Co(II),andCu(II)complexesincorporating2-pyrazinecarboxylicacid:Synthesis,characterization,electrochemicalevaluation,andcatalyticactivityforthesynthesisof2H-indazolo[2,1-b]phthalazine-triones
%A Behnaz Afzalian
%A Joel T. Mague
%A Maryam Mohamadi
%A S. Yousef Ebrahimipour
%A Behjat Pour amiri
%A Esmat Tavakolinejad Kermani
%J ´ß»¯Ñ§±¨
%P 1101-1108
%D 2015
%R 10.1016/S1872-2067(14)60318-1
%X £¿Threecomplexescontaining2-pyrazinecarboxylate(pzca-),including[Ni(pzca)2(H2O)2],[Co(pzca)2(H2O)2],and[Cu(pzca)2(H2O)2],havebeensynthesizedandcharacterizedusingphysicochemicalandspectroscopicmethods.Furthermore,thestructureofeachcomplexwasdeterminedbysingle-crystalX-raydiffraction.Allthreecomplexeshaveanoctahedralgeometry,wherethemetalionchelatedbytwocarboxylateoxygens,twonitrogenatomsbelongingtopyrazinicacidmolecules,andtwooxygenatomsoftwowatermolecules.Thecatalyticactivitiesofthesecomplexeswerealsoinvestigatedinthegreensynthesisof2H-indazolo[2,1-b]phthalazine-trionesbythereactionofhydrazinehydratewithanarylaldehyde,phthalicanhydride,anddimedoneinaceticacid.
%K 2-Pyrazinecarboxylatecomplexe
%K ONbidentateligand
%K X-raycrystalstructure
%K Cyclicvoltammetry
%K 2H-indazolo[2
%K 1-b]phthalazine-triones
%U http://www.chxb.cn/CN/abstract/abstract21598.shtml