%0 Journal Article
%T Selectiveoxidationofalcoholsovercopperzirconiumphosphate
%A Abdol R. Hajipour
%A Hirbod Karimi
%J ´ß»¯Ñ§±¨
%P 1529-1533
%D 2014
%R 10.1016/S1872-2067(14)60096-6
%X £¿Thecatalyticactivityofcopperzirconiumphosphate(ZPCu)intheselectiveoxidationofalcoholstotheircorrespondingketonesoraldehydes,usingH2O2asanoxidizingagent,wasstudied.Theoxidationreactionwasperformedwithoutanyorganicsolvent,phase-transfercatalyst,oradditive.Stericfactorsassociatedwiththesubstratesinfluencedthereaction.ThecatalystwascharacterizedusingX-raydiffraction,inductivelycoupledplasmaatomicemissionspectroscopy,energy-dispersiveX-rayspectroscopy,andscanningelectronmicroscopy.Itwasshownthattheinterlayerdistanceincreasedfrom0.74to0.80nmandthecrystallinitywasreducedafterCu2+intercalationintothelayers.Thiscatalystcanberecoveredandreusedthreetimeswithoutsignificantlossofactivityandselectivity.
%K Copperzirconiumphosphate
%K Selectiveoxidation
%K Solidcatalyst
%K Alcohol
%U http://www.chxb.cn/CN/abstract/abstract21379.shtml