%0 Journal Article
%T PureandNi-substitutedCo3O4spinelcatalystsfordirectN2Odecomposition
%A Bahaa M. Abu-Zied
%A Soliman A. Soliman
%A Sarah E. Abdellah
%J ´ß»¯Ñ§±¨
%P 1105-1112
%D 2014
%R 10.1016/S1872-2067(14)60058-9
%X £¿AseriesofNixCo1-xCo2O4(0¡Üx¡Ü1)spinelcatalystswerepreparedbytheco-precipitationmethodandusedfordirectN2Odecomposition.Thedecompositionpathwayoftheparentprecipitateswascharacterizedbythermalanalysis.Thecatalystswerecalcinedat500¡æfor3handcharacterizedbypowderX-raydiffraction,Fouriertransforminfrared,andN2adsorption-desorption.NickelcobaltitespinelwasformedinthesolidstatereactionbetweenNiOandCo3O4.TheN2OdecompositionmeasurementrevealedsignificantincreaseintheactivityofCo3O4spineloxidecatalystwiththepartialreplacementofCo2+byNi2+.TheactivityofthisseriesofcatalystswascontrolledbythedegreeofCo2+substitutionbyNi2+,spinelcrystallitesize,catalystsurfacearea,presenceofresidualK+,andcalcinationtemperature.
%K Nitrousoxidedecomposition
%K Spinel
%K Cobaltoxide
%K Greenhousegas
%K Nickelcobaltite
%U http://www.chxb.cn/CN/abstract/abstract21329.shtml