%0 Journal Article
%T SynthesisofNickelHexacyanoferrateNanoparticlesandTheirPotentialasHeterogeneousCatalystsfortheSolvent-FreeOxidationofBenzylAlcohol
%A Shah R. ALI
%A Prakash CHANDRA
%A Mamta LATWAL
%A Shalabh K. JAIN
%A Vipin K. BANSAL
%A Sudhanshu P. SINGH
%J ´ß»¯Ñ§±¨
%P 1844-1849
%D 2011
%R 10.1016/S1872-2067(10)60292-6
%X £¿Nickelhexacyanoferratenanoparticlesweresynthesizedandcharacterizedusingelementalanalysis,thermalanalysis,infraredspectroscopy,andX-raydiffraction.AFE-SEMimageofthenickelhexacyanoferrateshowedthatitconsistsofnearlysphericalparticleswithsizesrangingfrom30to70nm.Thesynthesizedmaterialwasfoundtobeaheterogeneouscatalystusefulforthesolvent-freeoxidationofbenzylalcoholwithH2O2asanoxidant.A36%conversionofbenzylalcoholtobenzaldehydewasachievedunderoptimizedreactionconditionsusingspecificparameterssuchastheamountofcatalyst,thetemperature,thebenzylalcoholtoH2O2molarratio,andthereactiontime.
%K hexacyanoferratenanoparticle
%K heterogeneouscatalyst
%K benzylalcohol
%K benzaldehyde
%U http://www.chxb.cn/CN/abstract/abstract20569.shtml