%0 Journal Article %T PhotocatalyticSynthesisofGoldNanoparticlesUsingPreysslerAcidandTheirPhotocatalyticActivity %A Ali AYATI %A Ali AHMADPOUR %A Fatemeh F. BAMOHARRAM %A Majid M. HERAVI %A Hamed RASHIDI %J ´ß»¯Ñ§±¨ %P 978-982 %D 2011 %R 10.1016/S1872-2067(10)60221-5 %X £¿£¿PreyssleracidH14[NaP5W30O110]wasusedasreducingagentandstabilizerforthesynthesisofgoldnanoparticlesbyphotolysisofAu(III)/Preyssleracid/propan-2-olsolution.Preyssleracidplaysboththeroleoftransferringelectronsfrompropan-2-oltoAu(III)andstabilizingthenanoparticles.Propan-2-olwasusedassacrificialreagentforthephotoformationofreducedPreyssleracid.Goldnanoparticles(AuNPs)werecharacterizedbyUV-Visspectroscopy,transmissionelectronmicroscopy(TEM),andparticlesizedistribution(PSD)measurements.ThesynthesizedAuNPshadauniformhexagonalmorphologyandtheirsizewasabout17nm.ThecatalyticperformanceoftheseNPsforphotodegradationofmethylorange(MeO)wasinvestigatedinaqueoussolution.UV-VisstudiesshowedthatAuNPscancatalyzephotodegradationofthisazodye.Thepseudo-first-orderrateconstantswerealsocalculatedforthisreaction. %K gold %K nanoparticle %K polyoxometalate %K Preyssleracid %K photodegradation %K methylorange %U http://www.chxb.cn/CN/abstract/abstract20440.shtml