%0 Journal Article %T The thermoanalytical, infrared and pyrolysis-gas chromatography-mass spectrometric sifting of poly (methyl methacrylate) in the presence of phosphorus tribromide %A Muhammad Arshad %A Khalid Masud %A Muhammad Arif %A Saeed-ur Rehman %A Jamshed H. Zaidi %A Muhammad Arif %A Aamer Saeed %A Tariq Yasin %J Natural Science %P 307-319 %@ 2150-4105 %D 2010 %I Scientific Research Publishing %R 10.4236/ns.2010.24039 %X The behaviour of poly(methyl methacrylate) was examined in the presence of phosphorus tri-bromide (PBr3) with varying concentrations. Films were cast from common solvent and subjected to TG, DTA, DTG, IR and Py-GC-MS for evaluating the degradation routes. Despite early decomposition of the blends, certain tempera-ture zones were identified for stabilization of the system. New products were found and mecha-nisms of their formation were proposed. Pyro-lysis of the blends was also carried out at dif-ferent temperatures to ascertain the nature of interaction between the constituents of the system. %K PMMA %K PBr3 %K Thermoanalytical Study %K IR Spectroscopy %K GC-MS Investigation %U http://www.scirp.org/journal/PaperInformation.aspx?PaperID=1724