%0 Journal Article %T Spin Properties of Very Shallow Nitrogen Vacancy Defects in Diamond %A B. K. Ofori-Okai %A S. Pezzagna %A K. Chang %A M. Loretz %A R. Schirhagl %A Y. Tao %A B. A. Moores %A K. Groot-Berning %A J. Meijer %A C. L. Degen %J Physics %D 2012 %I arXiv %R 10.1103/PhysRevB.86.081406 %X We investigate spin and optical properties of individual nitrogen-vacancy centers located within 1-10 nm from the diamond surface. We observe stable defects with a characteristic optically detected magnetic resonance spectrum down to lowest depth. We also find a small, but systematic spectral broadening for defects shallower than about 2 nm. This broadening is consistent with the presence of a surface paramagnetic impurity layer [Tisler et al., ACS Nano 3, 1959 (2009)] largely decoupled by motional averaging. The observation of stable and well-behaved defects very close to the surface is critical for single-spin sensors and devices requiring nanometer proximity to the target. %U http://arxiv.org/abs/1201.0871v2