%0 Journal Article
%T Chiral Pinwheel Heterojunctions Self Assembled from C60 and Pentacene
%A Joseph A. Smerdon
%A Rees B. Rankin
%A Jeffrey Greeley
%A Nathan Guisinger
%A Jeffrey Guest
%J Physics
%D 2013
%I arXiv
%R 10.1021/nn304992c
%X We demonstrate the self-assembly of C$_{60}$ and pentacene (Pn) molecules into acceptor-donor heterostructures which are well-ordered and -- despite the high degree of symmetry of the constituent molecules -- {\it chiral}. Pn was deposited on Cu(111) to monolayer coverage, producing the random-tiling ($R$) phase as previously described. Atop $R$-phase Pn, post-deposited C$_{60}$ molecules cause rearrangement of the Pn molecules into domains based on chiral supramolecular `pinwheels'. These two molecules are the highest-symmetry achiral molecules so far observed to coalesce into chiral heterostructures. Also, the chiral pinwheels (composed of 1 C$_{60}$ and 6 Pn each) may share Pn molecules in different ways to produce structures with different lattice parameters and degree of chirality. High-resolution scanning tunneling microscopy (STM) results and knowledge of adsorption sites allow the determination of these structures to a high degree of confidence. The measurement of chiral angles identical to those predicted is a further demonstration of the accuracy of the models. Van der Waals density functional theory calculations reveal that the Pn molecules around each C$_{60}$ are torsionally flexed around their long molecular axes and that there is charge transfer from C$_{60}$ to Pn in each pinwheel.
%U http://arxiv.org/abs/1309.0335v1