%0 Journal Article
%T Drastic Resistivity Reduction of CVD-TiO<sub>2</sub> Layers by Post-Wet-Treatment in HCl Solution
%A Satoshi Yamauchi
%A Kazuhiro Ishibashi
%A Sakura Hatakeyama
%J Journal of Crystallization Process and Technology
%P 24-30
%@ 2161-7686
%D 2015
%I Scientific Research Publishing
%R 10.4236/jcpt.2015.51004
%X Poly-crystalline anatase TiO<sub>2</sub> layer fabricated by LPCVD using titanium-tetra-iso-propoxide and NbF<sub>5</sub> in H<sub>2</sub>-ambient was treated in conc.-HCl solution after thin layer of IIIb-group metal was deposited on the TiO<sub>2</sub> layer. Resistivity of the as-deposited layer about 1 ¡Á 10<sup>-1</sup> ¦¸·cm was drastically reduced to 3 ¡Á 10<sup>-3</sup> ¦¸·cm by the wet-treatment using indium. Temperature dependence of the resistivity increased with temperature above 100 K for the wet-treated layer was quite different from that decreased above 100 K for the as-deposited layer, whereas the resistivity was saturated at lower temperatures. The resistivity at room-temperature was decreased with the thickness before the wet-treatment but independent on the thickness above 100 nm for the wet-treated layer. Indium was more effective for the resistivity reduction than gallium but aluminum was not useful for the treatment. As the results that the wet-treatment using indium was examined for the TiO<sub>2</sub> layers deposited by various conditions, the optimum deposition condition to reduce the resistivity of the layer after the wet-treatment was clearly different from that for the as-deposited layer.
%K LPCVD
%K Poly-Crystalline TiO<
%K sub>
%K 2<
%K /sub>
%K Post Wet-Treatment
%K Low Resistive TiO<
%K sub>
%K 2<
%K /sub>
%U http://www.scirp.org/journal/PaperInformation.aspx?PaperID=53296