%0 Journal Article
%T Transition Metal Doped MnO<sub>x</sub>-CeO<sub>2</sub> Catalysts by Ultrasonic Immersing for Selective Catalytic Reduction of NO with NH<sub>3</sub> at Low Temperature
%A Jinshuo Qiao
%A Ning Wang
%A Cuiya Zhuang
%A Kening Sun
%J Modern Research in Catalysis
%P 13-19
%@ 2168-4499
%D 2015
%I Scientific Research Publishing
%R 10.4236/mrc.2015.41002
%X Transition metals doped Mn-based catalysts were prepared via ultrasonic immersing method for the selective catalytic reduction (SCR) of NOx from fuel gas. The Catalysts¡¯ DeNOx efficiency and tolerance to sulfur were investigated in the paper. XRD results demonstrate high dispersion of Mn, Ce and M (Pr, Y, Zr, W) elements on TiO2 carrier, which is favor for reduction of active materials content. Mn-Ce-W catalyst presents uniform particle size about 500 nm to 800 nm from SEM pictures and shows the best NOx conversion of 93.2% at 200°C and 98.4% at 250°C, respectively. Sulfur tolerance analysis indicated that transition metals M can improve the catalysts¡¯ performance when 0.01% SO2 exists in the fuel gas, because metal doping into the Mn-Ce catalyst can inhibit the sulfate deposition, especially metal sulfate, on the catalyst, which can be seen from the Fourier infrared spectrum.
%K Mn-Based Catalysts
%K Ultrasonic Immersing Method
%K Selective Catalytic Reduction
%K Sulfur Tolerance
%U http://www.scirp.org/journal/PaperInformation.aspx?PaperID=53039