%0 Journal Article
%T Synthesis, Spectral and Antimicrobial Studies of Bis (Cyclopentadienyl) Titanium (IV) Bis (O,O¡¯-Dialkyl and Alkylenedithiophosphate) Complexes
%A Adnan A. S. El Khaldy
%A Florence Okafor
%A Alaa M. Abu Shanab
%J International Journal of Organic Chemistry
%P 339-346
%@ 2161-4695
%D 2014
%I Scientific Research Publishing
%R 10.4236/ijoc.2014.45037
%X A new complexes of Cp<sub>2</sub>Ti[S<sub>2</sub>P(OR)<sub>2</sub>]<sub>2</sub> (where R = Et, Pr-n, Pr-i, Bu-i and Ph) and Cp<sub>2</sub>Ti[S<sub>2</sub>POGO]<sub>2</sub> (where G = -CH<sub>2</sub>CMe<sub>2</sub>CH<sub>2</sub>-, -CH<sub>2</sub>CEt<sub>2</sub>CH<sub>2</sub>-
and -CMe<sub>2</sub>CMe<sub>2</sub>-) were prepared by the dropwise addition of
the appropriate <span>O</span>,<span>O¡¯</span>-dialkyl or -alkylenedithiophosphoric
acid to biscyclopentadienyl titanium dichloride in 1:2 molar ratio and refluxed
in benzene solution. These novel deep red colored complexes were characterized
by elemental analyses, molecular weight measurements and spectroscopic
techniques (IR., NMR <sup>1</sup>H,<sup> 13</sup>C and <sup>31</sup>P NMR). These
titanium (IV) dithio complexes have also been screened for their antibacterial
activities.
%K Titanium (IV) Dialkyl and Alkylenedithiophosphate Complexes
%U http://www.scirp.org/journal/PaperInformation.aspx?PaperID=52837