%0 Journal Article
%T 动态硫化PP/EPDM共混体系固化与结晶动力学研究
Study on Solidification Behavior and
Crystallization Kinetics of Dynamically-Vulcanized PP/EPDM Blends
%A 黄亮
%A 胡磊
%A 杨斌
%A 苗继斌
%A 夏茹
%A 钱家盛
%A 曹明
%J Material Sciences
%P 205-210
%@ 2160-7621
%D 2014
%I Hans Publishing
%R 10.12677/MS.2014.45029
%X
通过动态硫化方法制备了聚丙烯/三元乙丙橡胶(PP/EPDM)共混体系,研究了不同橡塑比、SiO2添加量等因素对PP/EPDM共混体系的力学性能、导热及结晶动力学的影响。研究表明,随着EPDM含量增加,共混物冷却速率较纯PP有显著提高;随着EPDM的加入,使得PP半晶时间(t1/2)显著缩短,EPDM在共混体系的冷却结晶过程中对PP具有良好的成核促进作用。<br/>The PP/EPDM blends were prepared using dynamical vulcanization. The effects of different plas-tic/rubber ratios, content of SiO2 on the mechanical properties, thermal conductivity as well as crystallization kinetics were intensively investigated. Our findings showed that the cooling rate of the PP/EPDM blends increased with increasing EPDM content. With the addition of EPDM, the crystallization half time (t1/2) was shortened, suggesting that the existence of EPDM phase was fa-vorable to the improvement on PP nucleation during the cooling period from melt state.
%K 动态硫化,PP/EPDM,共混物,二氧化硅,结晶动力学
Dynamic Vulcanization
%K PP/EPDM
%K Blend
%K SiO2
%K Crystallization Kinetics
%U http://www.hanspub.org/journal/PaperInformation.aspx?PaperID=14155