%0 Journal Article
%T CaSO4晶须/天然橡胶复合材料的制备与性能研究<br>Study on Properties and Preparation of Caso4-Whisker/Rubber Composites
%A 吴晓宇
%A 罗筑
%A 杨诗润
%A 夏忠林
%A 于杰
%J Hans Journal of Chemical Engineering and Technology
%P 65-71
%@ 2161-8852
%D 2013
%I Hans Publishing
%R 10.12677/HJCET.2013.32011
%X 用KH-560表面接枝处理CaSO4晶须，采用母炼胶法制备了CaSO4晶须/天然橡胶复合材料。研究了CaSO4晶须/NR复合材料的力学、磨耗及动态力学性能，与未处理的CaSO4晶须/NR复合材料性能比较，发现CaSO4晶须经表面接枝处理后，复合材料的拉伸强度、撕裂强度、300%定伸应力和邵尔A硬度均有提高，断裂伸长率和磨耗量减小，且横向磨损量比纵向小，其中经KH-560处理的晶须添加量为3份时复合材料横向磨损量为0.6499 cm？3/1.61km，磨耗性能最佳，而基体橡胶磨损量为0.7372 cm？3/1.61km。并用SEM对橡胶磨屑和橡胶磨损表面形貌用进行了分析；DMA表明CaSO4晶须经KH-560表面接枝处理后界面作用增强。<br />
In the experimental test CaSO4-whisker being treated by agent KH-560 has been added to the rubber com-posites. The mechanical properties, abrasion and attrition behavior and dynamic mechanical properties of the rubber composites have been studied, comparing with the rubber composites adding the CaSO4-whisker without coupling agent KH-560. The SEM patterns of abrasive dust and the rubber composites worm surface were analysed. The experiments showed that adding CaSO4-whisker being treated by coupling agent KH-560 to rubber composites got better interfacial adhesion，wear resistant, tensile strength, tear strength, stress at 300% elongation and shore hardness. Then wear resis-tant of rubber composites adding 3% CaSO4-whisker (weight ratio of the whisker to the rubber) being treated by cou-pling agent KH-560 was the best (0.6499 cm？3/1.61km, compared with 0.7372 cm？3/1.61km of rubber composites without CaSO4-whisker). DMA indicates that rubber composites adding CaSO4-whisker being treated by agent KH-560 have better interface adhesion than rubber composites adding CaSO4-whisker without treated.
%K CaSO4晶须；天然橡胶；液体聚异戊二烯橡胶；偶联剂；界面粘合<br>Caso4-Whisker
%K Natural Rubber
%K Liquid Isoprene Rubber
%K Coupling Agent
%K Interfacial Adhesion
%U http://www.hanspub.org/journal/PaperInformation.aspx?PaperID=9604