%0 Journal Article %T Surface Effect of Silica Nano-Particles with Different Size on Thermotropic Liquid Crystalline Polyester Composites %A Hiroki Fukatsu %A Masaaki Kuno %A Yasuhiro Matsuda %A Shigeru Tasaka %J World Journal of Nano Science and Engineering %P 35-41 %@ 2161-4962 %D 2014 %I Scientific Research Publishing %R 10.4236/wjnse.2014.42006 %X
Interface properties of nano-silica/thermotropic liquid crystalline polyesters (TLCP) composites were investigated by X-ray diffraction analysis and differential scanning calorimetory. The crystallinity of TLCP in the composites drastically decreased with an increase of nano-silica content, depending on the surface area of the silica particles. Little size effects (40 - 400 nm) in the particles and strong interaction between silica surface and the C=O moieties of TLCP were observed by IR analysis. The glass transition temperature of TLCP (<20 nm) in silica surface increased about 20<sup>ĄŁ</sup>C higher than that in bulk.
%K Component %K Nano-Silica %K Thermotropic Crystalline Polyester %K Interface %K Differential Scanning Calorimetry %U http://www.scirp.org/journal/PaperInformation.aspx?PaperID=45740