%0 Journal Article
%T Carbon Derived from Jatropha Seed Hull as a Potential Green Adsorbent for Cadmium (II) Removal from Wastewater
%A Masita Mohammad
%A Zahira Yaakob
%A Siti Rozaimah Sheikh Abdullah
%J Materials
%D 2013
%I MDPI AG
%R 10.3390/ma6104462
%X Carbon from jatropha seed hull (JC) was prepared to study the adsorption of cadmium ions (Cd 2+) from aqueous solutions under various experimental conditions. Batch equilibrium methods have been used to study the influences of the initial metal ion concentration (0.5每50 ppm), dosage (0.2每1 g), contact time (0每300 min), pH (2每7), and temperature (26每60 ∼C) on adsorption behavior. It has been found that the amount of cadmium adsorbed increases with the initial metal ion concentration, temperature, pH, contact time, and amount of adsorbent. A kinetic study proved that the mechanism of Cd 2+ adsorption on JC followed a three steps process, confirmed by an intraparticle diffusion model: rapid adsorption of metal ions, a transition phase, and nearly flat plateau section. The experimental results also showed that the Cd 2+ adsorption process followed pseudo-second-order kinetics. The Langmuir and Freundlich adsorption isotherm models were used to describe the experimental data, with the former exhibiting a better correlation coefficient than the latter ( R 2 = 0.999). The monolayer adsorption capacity of JC has been compared with the capacities of the other reported agriculturally-based adsorbents. It has been clearly demonstrated that this agricultural waste generated by the biofuel industry can be considered a potential low-cost adsorbent for the removal of Cd 2+ from industrial effluents.
%K adsorption activity
%K carbon
%K jatropha seed hull
%K cadmium
%K kinetic and isotherm model
%U http://www.mdpi.com/1996-1944/6/10/4462