%0 Journal Article
%T Thermal Conductivity of Cu-Cr-Zr-Ti Alloy in the Temperature Range of 300¨C873£¿K
%A S. Chenna Krishna
%A N. Supriya
%A Abhay K. Jha
%A Bhanu Pant
%A S. C. Sharma
%A Koshy M. George
%J ISRN Metallurgy
%D 2012
%R 10.5402/2012/580659
%X In the present investigation, thermal conductivity of Cu-Cr-Zr-Ti alloy was determined as the product of the specific heat ( ), thermal diffusivity ( ), and density ( ) in the temperature range of 300¨C873£¿K. The experimental results showed that the thermal conductivity of the alloy increased with increase in temperature up to 873£¿K and the data was accurately modeled by a linear equation. For comparison, thermal conductivity was also evaluated for OFHC copper in the same temperature range. The results obtained were discussed using electrical conductivity and hardness measurements made at room temperature. Transmission electron microscopy (TEM) was done to understand the microstructural changes occurring in the sample after the test. Wiedemann-Franz-Lorenz law was employed for calculating electronic and phonon thermal conductivity using electrical conductivity. On the basis of studies conducted it was deduced that in situ aging may be one of the reasons for the increase in thermal conductivity with temperature for Cu-Cr-Zr-Ti alloy. 1. Introduction Cu-Cr-Zr alloy is a candidate material for high heat flux applications like the inner wall of a thrust chamber and the first wall of nuclear reactor owing to its high conductivity and strength [1, 2]. The high conductivity of the alloy is attributed to the low solubility of Cr and Zr in copper at room temperature [3], while the strength is due to the precipitation of Cr and Cu5Zr in copper matrix [4, 5]. Zirconium plays an additional role of fixing elemental sulphur and suppresses dynamic embrittlement [6]. The alloy used in the present study is modified by the addition of titanium of Cu-Cr-Zr alloy. Titanium plays a role similar to that of zirconium in Cu-Cr-Zr alloy in suppressing dynamic embrittlement by fixing elemental sulphur as titanium sulphide [7]. Limited literature is available on mechanical properties, microstructure and thermal properties of Cu-Cr-Zr-Ti alloy. Lack of thermal conductivity data for the alloy at elevated temperature promoted us to design experiments to evaluate the same in the temperature of 300¨C873£¿K. 2. Experimental Procedure Hot rolled and annealed plate of Cu-0.61Cr-0.038Zr-0.029Ti-0.003Fe (wt%) alloy was used in the present study. Small pieces cut from the plate were used for hardness, thermal, and electrical conductivity measurement. In addition, properties of OFHC copper (C10100) were evaluated in the annealed condition. OFHC copper represents the pure form of copper, and the effect of alloying elements (Cu-Cr-Zr-Ti) can be better understood by comparison. Thermal
%U http://www.hindawi.com/journals/isrn.metallurgy/2012/580659/