%0 Journal Article %T Complements to the Theoretical Treatments of the Electron Collision with : An R -Matrix Approach %A V. Stancalie %J Journal of Spectroscopy %D 2013 %R 10.1155/2013/820635 %X This paper presents new refined results from the theoretical treatment of electron collision with the Fe-peak element Co3+. We have investigated the relevance of relativistic effects on the accurate representation of the target electron wave functions within the Breit-Pauli R-matrix approach. The calculated values for fine-structure levels are compared with the available experimental data in Atomic Structure Database of the National Institute for Standards and Technology. The agreement between the calculated and the experimental data is reasonably good, the energy difference average percentage of the low-lying levels usually agreeing to within 3.6% of each other. For completeness, we summarize herein the existing theoretical R-matrix treatments intended specifically to explore the role of including configuration interaction wave functions both in the target-state expansion, and in the ( )-electron quadratically integrable function expansion. To the best of our knowledge, the work reported herein describes for the first time a detailed calculation for this atomic system, and the results are relevant to the laboratory and astrophysical plasmas. 1. Introduction The present work aims to provide atomic data and electron collision data for the Fe-peak element Co IV and to supply with additional information the studies on astrophysical opacities. The electron collision data for Fe, Ni, and Co elements, and their ions are important in line identification in stellar objects or in tokamak plasmas, since the collisional rate of deexcitation for metastable levels may be lower than the decay rate by magnetic dipole or electric quadrupole transitions, which become observable. Due to a lack of precise abundance values these data are of importance in the analysis of many astronomical spectra. The needed atomic data can be obtained in various approximations that differ in their demands on resources by several orders of magnitude. Ranges of validity of expansions and applicability of perturbation treatments must be established in order to obtain reliable data with the most economical methods. The R-matrix approach has enabled vast amounts of accurate electron and photon collision data which have had wide applications.£¿£¿The recent volume by Burke [1] provides both a general review of the R-matrix method as applied to atomic and molecular collision processes and a very extensive bibliography. The R-matrix treatments [2¨C9] have provided results for electron collision with most of the ions of Fe, Ni and Co such as: Fe I, Fe II, Fe III, Fe IV, Fe V, Fe VI, Fe VII, Co V, Co %U http://www.hindawi.com/journals/jspec/2013/820635/