%0 Journal Article
%T Polystyrene Microbeads by Dispersion Polymerization: Effect of Solvent on Particle Morphology
%A Lei Jinhua
%A Zhou Guangyuan
%J International Journal of Polymer Science
%D 2014
%I Hindawi Publishing Corporation
%R 10.1155/2014/703205
%X Polystyrene microspheres (PS) were synthesized by dispersion polymerization in ethanol/2-Methoxyethanol (EtOH/EGME) blend solvent using styrene (St) as monomer, azobisisobutyronitrile (AIBN) as initiator, and PVP (polyvinylpyrrolidone) K-30 as stabilizer. The typical recipe of dispersion polymerization is as follows: St/Solvent/AIBN/PVP = 10ˋg/88ˋg/0.1ˋg/2ˋg. The morphology of polystyrene microspheres was characterized by the scanning electron microscopy (SEM) and the molecular weights of PS particles were measured by the Ubbelohde viscometer method. The effect of ethanol content in the blend solvent on the morphology and molecular weight of polystyrene was studied. We found that the size of polystyrene microspheres increased and the molecular weight of polystyrene microspheres decreased with the decreasing of the ethanol content in the blend solvent from 100ˋwt% to 0ˋwt%. What is more, the size monodispersity of polystyrene microspheres was quite good when the pure ethanol or pure 2-Methoxyethanol was used; however when the blend ethanol/2-Methoxyethanol solvent was used, the polystyrene microspheres became polydisperse. We further found that the monodispersity of polystyrene microspheres can be significantly improved by adding a small amount of water into the blend solvent; the particles became monodisperse when the content of water in the blend solvent was up to 2ˋwt%. 1. Introduction Micrometer-size monodisperse polymer particles have a wide variety of scientific and technological applications, such as standard calibration, biomedical and clinical diagnosis, high-performance liquid chromatography (HPLC) fillers, catalyst carriers, coatings and ink additives, information storage materials, and colloidal crystals [1, 2]. Micron-size monodisperse particles were usually difficult to obtain because this size is in-between the diameter range of particles produced by conventional emulsion polymerization (0.06每0.7ˋ米m) in a batch process [3每6] and suspension polymerization (50每1000ˋ米m) [7每11]. Dispersion polymerization is an attractive method for producing micron-size monodisperse polymer particles in a single batch process. Great progress in this field has been achieved over the past three decades [12每21]. Dispersion polymerization in organic hydrocarbon media was first developed by Barrett [22]. Dispersion polymerization may be defined as a type of precipitation polymerization in which one carries out the polymerization of a monomer in the presence of a suitable polymeric stabilizer soluble in the reaction medium. The solvent selected as the reaction
%U http://www.hindawi.com/journals/ijps/2014/703205/