%0 Journal Article %T A Highly Luminous LiCaPO<sub>4</sub>:Eu<sup>2+</sup> Phosphor Synthesized by a Solution Method Employing a Water-Soluble Phosphate Ester %A Minsung Kim %A Makoto Kobayashi %A Hideki Kato %A Masato Kakihana %J Optics and Photonics Journal %P 13-18 %@ 2160-889X %D 2013 %I Scientific Research Publishing %R 10.4236/opj.2013.36A003 %X

A LiCaPO4:Eu2+ phosphor with high photoluminescence was synthesized using a polymerizable complex (PC) method employing a water-soluble polyethylene glycol-conjugated phosphate ester (PEG-P). PEG-P could be obtained from a reaction among polyethylene glycol 300, phosphorus pentoxide, and pyrophosphoric acid. The PEG-P prepared was stable in an aqueous condition. A transparent solution and gel were obtained when the PEG-P was used as a source of P during the PC method, whereas the use of H3PO4 caused an undesirable precipitate. The LiCaPO4:Eu2+ obtained via the PC method employing the PEG-P showed higher emission intensity than those synthesized by a solid state reaction method and the PC method employing H3PO4. The high luminescence properties of the sample synthesized using the PEG-P may be attributed to high homogeneity of constituents in the sample.

%K Solution Method %K Stable Phosphate Ester %K Homogeneity %K LiCaPO< %K sub> %K 4< %K /sub> %K :Eu< %K sup> %K 2+< %K /sup> %U http://www.scirp.org/journal/PaperInformation.aspx?PaperID=38498