%0 Journal Article
%T De-oxygenation of CO2 by using Hydrogen, Carbon and Methane over Alumina-Supported Catalysts
%A R.Y. Raskar
%A K.B. Kale
%A A.G. Gaikwad
%J Bulletin of Chemical Reaction Engineering & Catalysis
%D 2012
%I Diponegoro University
%R 10.9767/bcrec.7.1.1631.59-69
%X The de-oxygenation of CO2 was explored by using hydrogen, methane, carbon etc., over alumina supported catalysts. The alumina-supported ruthenium, rhodium, platinum, molybdenum, vanadium and magnesium catalysts were first reduced in hydrogen atmosphere and then used for the de-oxygenation of CO2. Furthermore, experimental variables for the de-oxygenation of CO2 were temperature (range 50 to 650 oC), H2/CO2 mole ratios (1.0 to 5), and catalyst loading (0.5 to 10 wt %). During the de-oxygenation of CO2 with H2 or CH4 or carbon, conversion of CO2, selectivity to CO and CH4 were estimated. Moreover, 25.4 % conversion of CO2 by hydrogen was observed over 1 wt% Pt/Al2O3 catalyst at 650 oC with 33.8 % selectivity to CH4. However, 8.1 to 13.9 % conversion of CO2 was observed over 1 wt% Pt/Al2O3 catalyst at 550 oC in the presence of both H2 and CH4. Moreover, 42.8 to 79.4 % CH4 was converted with 9 to 23.1 % selectivity to CO. It was observed that the de-oxygenation of CO2 by hydrogen, carbon and methane produced carbon, CO and CH4.   2012 BCREC UNDIP. All rights reserved Received: 6th February 2012; Revised: 23rd April 2012; Accepted: 24th April 2012 [How to Cite: R. Y. Raskar, K. B. Kale, A. G. Gaikwad. (2011). De-oxygenation of CO2 by using Hydrogen, Carbon and Methane over Alumina-Supported Catalysts. Bulletin of Chemical Reaction Engineering & Catalysis, 7 (1): 59-69. doi:10.9767/bcrec.7.1.1631.59-69] [How to Link / DOI: http://dx.doi.org/10.9767/bcrec.7.1.1631.59-69 ] | View in
%K De-oxygenation of carbon dioxide
%K hydrogen and methane
%K ruthenium
%K rhodium
%K platinum molybdenum
%K vanadium
%K magnesium
%K and alumina ¡ª supported catalysts
%U http://ejournal.undip.ac.id/index.php/bcrec/article/view/1631