%0 Journal Article
%T SYNTHESIS, STRUCTURE AND PROPERTIES OF [GD(C6N0(2)H5)3(H(2)0)2](2N) (NH(5)0(2))(NZNCL5)(2NZNCL4) (2NH(2)0) WITH STRONG FLUORESCENCE
%A YI-MING XIE
%A JI-HUAI WU
%J Journal of the Chilean Chemical Society
%D 2008
%I Sociedad Chilena de Qu¨Şmica
%X A novel one-dimensional metal-isonicotinato inorganic-organic hybrid complex ]GD(C6N0(2)H5)3(H(2)0)2](2N) (NH(5)0(2))(NZNCL5)(2NZNCL4) (2NH(2)0) (1) has been successfully synthesized via hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. Complex 1 is characteristic of a novel one-dimensional polycationic chain-like structure and unprecedented ZnCl53~species. Optical absorption spectra of 1 reveal the presence of an optical gap of 3.35 eV. Photoluminescent investigation reve¨˘is that the title complex displays a strong blue-light fluorescent emission band.
%K gadolinium
%K lanthanide
%K photoluminescence
%U http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000400007