%0 Journal Article
%T The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate
%A MLADJEN L. MICEVIC
%A SLOBODAN D. PETROVIC
%A MILICA M. MISIC-VUKOVIC
%J Journal of the Serbian Chemical Society
%D 2000
%I Serbian Chemical Society
%X The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate (soman) was examined with a series of alkoxides and in corresponding alcohols: methanol, ethanol, 1-propanol, 2-propanol, 2-methoxyethanol and 2-ethoxyethanol. Soman reacts with the used alkoxides in a second order reaction, first order in each reactant. The kinetics of the reaction between 1,2,2-trimethylpropyl-methylfluorophosphonate and ethanol in the presence of diethylenetriamine was also examined. A third order reaction rate constant was calculated, first order in each reactant. The activation energy, frequency factor and activation entropy were determined on the basis of the kinetic data.
%K decontamination
%K alcoholysis
%K 1
%K 2
%K 2-trimethylpropyl-methylfluorophosphonate
%K soman
%K alkoxides and diethylenetriamine
%U http://www.shd.org.yu/HtDocs/SHD/Vol65/No12-Pdf/JSCS12-03.pdf