%0 Journal Article
%T SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENE
%A J.F ARANEDA
%A S SALINAS
%A D MAC-LEOD-CAREY
%A A MU£¿OZ-CASTRO
%J Journal of the Chilean Chemical Society
%D 2009
%I Sociedad Chilena de Qu¨ªmica
%X This work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by reduction with Mg/HgCl2. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.
%K s-indaceno
%K zirconium dicarbonyl
%K zirconocene
%K DFT
%U http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000300014