%0 Journal Article
%T Carbonylative Coupling of 4,4กฏ-Diiodobiphenyl Catalyzed by Pd(NHC) Complex
%A Do-Hun Lee
%A Jung-Tai Hahn
%A Dai-Il Jung
%J Green and Sustainable Chemistry
%P 15-18
%@ 2160-696X
%D 2013
%I Scientific Research Publishing
%R 10.4236/gsc.2013.31003
%X <p>
	<span>To develop a luminescent material with high color
purity, luminous efficiency, and stability, we synthesized diketone by
carbonylative Suzuki coupling in the presence of Pd(NHC) complex as the
catalyst. Carbonylative coupling of 4,4</span><span>กฏ</span><span>-diiodobiphenyl and
phenylboronic acid was investigated to study in detail the catalytic ability of
the Pd(NHC) complex. Reactions were carried out using both CO and metal
carbonyls. Bis-(1,3-dihydro-1,3-dimethyl-2H-imidazol-</span><span> </span><span>2-ylidene) diiodo
palladium was used as the catalytic complex. Reaction products biphenyl-4,4</span><span>กฏ</span><span>-diylbis
(phenyl-</span><span> </span><span>methanone) 3 and (4</span><span>กฏ</span><span>-iodobiphenyl-4-yl)(phenyl) methanone 4<b> </b>were obtained as a result of CO
insertion into the palla</span><span>dium(II)-aryl bond. However, when
pyridine-4-yl boronic acid was used in place of phenylboronic acid as the
starting reagent, synthetic reaction yielding 3 and 4<b> </b>were found not to occur.</span><span></span> 
</p>
%K Carbonylative Coupling
%K Metal Carbonyl
%K Pd(NHC) Complex
%K 4
%K 4กฏ-Diiodobiphenyl
%K Phenylboronic Acid
%U http://www.scirp.org/journal/PaperInformation.aspx?PaperID=28060