%0 Journal Article %T Effects of LaFeO3 Additions on the Dielectric and Ferroelectric Properties of (K0.5Na0.5)NbO3 Ceramics %A CHENG Hua-Lei %A DU Hong-Liang %A ZHOU Wan-Cheng %A LUO Fa %A ZHU Dong-Mei %J 无机材料学报 %D 2012 %I Science Press %R 10.3724/sp.j.1077.2012.12325 %X Pure (K0.5Na0.5)NbO3 and 0.98(K0.5Na0.5)NbO3-0.02LaFeO3 ceramics (abbreviated as KNN and 0.98KNN-0.02LF, respectively) were prepared by a solid state reaction approach, and their crystal structure, dielectric and ferroelectric properties were investigated. Pure KNN and 0.98KNN-0.02LF ceramics are the orthorhombic structure and pseudo-cubic perovskite structure, respectively. Dielectric measurements revealed that the dielectric permittivity curves of 0.98KNN-0.02LF ceramics present two anomalies compared with pure KNN: (i) The orthorhombic- tetragonal transition (TO-T) and the tetragonal-cubic transition (TT-C) shifts to lower temperatures. (ii) The phase transition temperature range around the temperature of the maximum dielectric permittivity (Tm) becomes more and more broad. In addition, 0.98KNN-0.02LF ceramics exhibited a very stable temperature dependence of dielectric permittivity with permittivity maximum near 2000 and dielectric loss less than 4% in the temperature range of 0–400 The relaxation behavior of the 0.98KNN-0.02LF ceramics is interpreted in terms of polar nanoregions (PNRs) caused by cations disorder. The P-E hysteresis loops further confirms the relaxor behavior in 0.98KNN-0.02LF ceramics. %K
(K0.5Na0.5)NbO3 %K dielectric properties %K ferroelectric properties %K relaxor properties %K lead-free ceramics
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