%0 Journal Article
%T Note on the formula of brunogeierite and the first bond-valence parameters for Ge2+
%A Cemp¨Ērek J
%A Groat L A
%J Journal of Geosciences
%D 2013
%I 
%R 10.3190/jgeosci.130
%X Brunogeierite is a rare Ge-mineral with a spinel-type structure. Inconsistences in the brunogeierite formula suggesting divalent germanium in its structure have occurred since its description. A review of the published data and bond-valence calculations show that the correct ideal end-member formula of brunogeierite is (Fe2+)2Ge4+O4. The mineral is newly classified as a nesogermanate member of the ringwoodite group (Strunz classification 9.AC.15). Formal correction of the brunogeierite formula and classification was approved by the IMA Commission on New Minerals, Nomenclature and Classification (IMA-CNMNC) as proposal IMA 11-A. To perform bond-valence calculations using divalent germanium, new bond-valence parameters for Ge2+-O (R0 = 1.778  , B = 0.37  ) and Ge2+-Cl (R0 = 2.156  , B = 0.37  ) were evaluated.
%K germanium
%K spinel-type structure
%K ringwoodite group
%K bond-valence model
%U http://www.jgeosci.org/content/jgeosci.130_cempirek.pdf