%0 Journal Article
%T Determination of Trace Amounts of Lead with ETAAS After Single Drop Microextraction and Dispersive Liquid Liquid Microextraction Methods
%A Efe£¿£¿nar M.
%A £¿ak£¿r P.
%A £¿at£¿ro£¿lu N.
%J E3S Web of Conferences
%D 2013
%I 
%R 10.1051/e3sconf/20130137001
%X Two liquid-phase microextraction procedures, single-drop microextraction (SDME) and dispersive liquid¨Cliquid microextraction (DLLME), have been developed for the determination of lead by electrothermal atomic absorption spectrometry (ETAAS). Both methods were based on the formation of lead iodide-Rhodamine B complex which is in phosphoric acid medium. In the presence of KI, anionic lead iodide was complexed with Rhodamine B as an ion-association complex. Several factors that may be affected on the SDME and DLLME methods were optimized. In the optimum experimental conditions, the limit of detection (3s) and the enhancement factor were 0.008 ¦ÌgL 1 and 152 for SDME and 0.0129 ¦ÌgL 1 and 89 for DLLME respectively. The relative standard deviation (RSD) for eight replicate determinations of 0.25 ¦ÌgL 1 Pb was 4.6% for SDME and 0.5 ¦ÌgL 1 Pb was 2.9% for DLLME. The developed methods were validated by the analysis of certified reference materials, and applied successfully to the determination of lead in several water and food samples.
%K Lead
%K single drop microextraction
%K dispersive liquid liquid microextraction
%K ETAAS
%U http://dx.doi.org/10.1051/e3sconf/20130137001