%0 Journal Article
%T Soft combustion technique: Solution combustion synthesis and low-temperature combustion synthesis; to prepare Bi4Ti3O12 powders and bulk ceramics
%A Al-Amani Umar
%A Sreekantan S.
%A Fauzi Ahmad M.N.
%A Khairunisak A.R.
%J Science of Sintering
%D 2012
%I International Institute for the Science of Sintering, Beograd
%R 10.2298/sos1202211a
%X Bi4Ti3O12 (BTO) powders were synthesized using soft combustion techniques, specifically known as Solution Combustion Synthesis (SCS) and Low-temperature Combustion Synthesis (LCS). XRD results showed that the single phase BTO was obtained following calcinations at 800oC for the sample prepared using SCS; compared to after combustion, for the sample prepared using LCS. The TG/DTA showed a combustion temperature of around 252 - 280oC, which became stable with a single phase BTO at 500oC and above. Sintering was carried out at 1,100oC for 3 h, to determine the microstructures, grain orientation, relative density, dielectric, and ferroelectric properties, of the bulk ceramics. It was found that the bulk ceramics prepared using SCS exhibited elongated-like grains, strong (117)-preferred grain orientation, a relative density of 93.3%, ¦År = 320 - 360, tan ¦Ä = 0.03 - 0.1, Pr = 6.8 ¦ÌC/cm2, and Ec = 20 kV/cm. Meanwhile, the bulk ceramics prepared using LCS showed plate-like grains, strong c-preferred grain orientation, a relative density of 83%, ¦År = 143 - 195, tan ¦Ä = 0.01 - 0.38, Pr = 5.9 ¦ÌC/cm2, and Ec = 30 kV/cm.
%K Bi4Ti3O12
%K combustion synthesis
%K grain orientation
%K dielectric
%K ferroelectric
%U http://www.doiserbia.nb.rs/img/doi/0350-820X/2012/0350-820X1202211A.pdf