%0 Journal Article
%T 6,6'-(1E,1'E)-((1R,2R)-1,2-Diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl)ethynyl)phenol)
%A Thimo Huber
%A Lennart Niehues
%A Carlos Cativiela
%A M. G. Finn
%A David D¨Şaz D¨Şaz
%J Molbank
%D 2013
%I MDPI AG
%R 10.3390/M795
%X Functionalizable salen derivative, 6,6'-(1 E,1' E)-((1 R,2 R)-1,2-diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2- tert-butyl-4-((trimethylsilyl) ethyn-yl)phenol) ( 3), was synthesized by condensation between (1 R,2 R)-1,2-diphenylethane-1,2-diamine ( 2) and 3- tert-butyl-2-hydroxy-5-((trimethylsilyl)ethynyl) benzaldehyde ( 1) under refluxing conditions. The title compound was characterized by 1H-NMR, 13C-NMR, FT-IR, high-resolution mass spectrometry, optical rotation and melting point determination.
%K salen ligands
%K chiral 1
%K 2-diamines
%K alkynes
%K nucleophilic addition
%U http://www.mdpi.com/1422-8599/2013/1/M795