%0 Journal Article
%T trans-Carbonylchloridobis(tri-p-tolylphosphine)rhodium(I) acetone solvate
%A Fabio Lorenzini
%A Brian O. Patrick
%A Brian R. James
%J Acta Crystallographica Section E
%D 2008
%I International Union of Crystallography
%R 10.1107/s1600536808003528
%X The title compound, [RhCl(C21H21P)2(CO)]¡¤C3H6O, was precipitated in trace yield from a reaction of RhCl(cod)(THP) with P(p-tol)3 in a 1:1 acetone-d6/CD3OD solution under a hydrogen atmosphere [p-tol = p-tolyl, THP = tris(hydroxymethyl)phosphine, P(CH2OH)3, and cod = 1,5-cyclooctadiene]. The complex displays a square-planar geometry around the RhI atom. The complex molecules and the acetone molecules are linked into a chain along the a axis by intermolecular C¡ªH...Cl and C¡ªH...O hydrogen bonds.
%U http://scripts.iucr.org/cgi-bin/paper?S1600536808003528