%0 Journal Article
%T Di-米2-acetato-1:2百2O:O∩;2:3百2O:O∩-bis(N,N∩-dimethylformamide)-1百O,3百O-bis{米2-2,2∩-[propane-1,3-diylbis(iminomethylene)]diphenolato-1百4O,N,N∩,O∩:2百2O,O∩;2百2O,O∩:3百4O,N,N∩,O∩-1,3-dinickel(II)-2-cadmium(II)
%A Leyla Tatar Yˋldˋrˋm
%A Orhan Atakol
%J Acta Crystallographica Section E
%D 2008
%I International Union of Crystallography
%R 10.1107/s1600536807067724
%X The crystal structure of the title compound, [Ni2Cd(C17H16N2O2)2(C2H3O2)2(C3H7NO)2], contains discrete centrosymmetric hetero-trinuclear molecules in which Ni/Cd atom pairs are triply bridged via O atoms from the SALPD2  [N,N∩-bis(salicylidene)-1,3-propanediaminate] and acetate ligands. The central CdII ion is in a distorted octahedral coordination environment formed by four O atoms from two SALPD2  ligands in the equatorial plane and two O atoms of two symmetry-related acetate ligands in the axial positions. The symmetry-related NiII ions are in slightly distorted octahedral environments, coordinated by two O and two N atoms from tetradendate SALPD2  ligands in the equatorial plane, while the axial positions are occupied by O atoms from a dimethylformamide and an acetate ligand. This results in the formation of three edge-shared octahedra in which the Ni...Cd distance is 3.1482 (15)  . The crystal structure is stabilized by weak C〞H...O hydrogen bonds.
%U http://scripts.iucr.org/cgi-bin/paper?S1600536807067724