%0 Journal Article
%T Bis(米-2-hydroxybenozato)-百3O,O∩:O∩;百3O:O,O∩-bis[(2-hydroxybenozato-百2O,O∩)(1,10-phenanthroline-百2N,N∩)cadmium(II)]
%A Qing-Yuan Shi
%A Zhi-Cheng Li
%A Zong-Sheng Cheng
%A Jing-Bo Tan
%J Acta Crystallographica Section E
%D 2008
%I International Union of Crystallography
%R 10.1107/s1600536808033886
%X The dinuclear title compound, [Cd2(C7H5O3)4(C12H8N2)2], is located on a crystallographic rotation twofold axis. The two CdII ions are connected by two tridentate bridging 2-hydroxybenzoate anions. Each CdII ion is seven-coordinated by five O atoms from three 2-hydroxybenzoate ligands and two N atoms from 1,10-phenanthroline. The 2-hydroxybenzoate molecules adopt two kinds of coordination mode, bidentate chelating and tridentate bridging每chelating. Intramolecular hydrogen bonds between hydroxy and carboxylate groups from 2-hydroxybenzoate groups and 羽每羽 stacking interactions between parallel 1,10-phenanthroline ligands [centroid每centroid distances = 3.707 (3) and 3.842 (3)  ] are observed. Furthermore, adjacent benzene rings from 2-hydroxybenzoate ligands are involved in 羽每羽 interactions with interplanar distances of 3.642 (3)  , thereby forming a chain along the a axis direction.
%U http://scripts.iucr.org/cgi-bin/paper?S1600536808033886