%0 Journal Article
%T Diaquabis(N,N-diethylnicotinamide-κN1)bis[4-(dimethylamino)benzoato-κO]cobalt(II)
%A Tuncer H&#246
%A kelek
%A Hakan Dal
%A Bar&#305
%A &#351
%A Tercan
%A &#214
%A zg&#252
%A r Aybirdi
%J Acta Crystallographica Section E
%D 2009
%I International Union of Crystallography
%R 10.1107/s1600536809030980
%X The title CoII complex, [Co(C9H10NO2)2(C10H14N2O)2(H2O)2], is centrosymmetric. It contains two dimethylaminobenzoate (DMAB) and two diethylnicotinamide (DENA) ligands and two water molecules, all of them being monodentate. The four O atoms in the equatorial plane around the Co atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of DENA ligands with the Co¡ªN distance of 2.1519 (11)   in the axial positions. The Co atom is displaced out of the least-squares plane of the carboxylate group by  0.781 (1)  . The dihedral angle between the carboxylate group and the adjacent benzene ring is 5.05 (7)¡ã, while the pyridine and benzene rings are oriented at a dihedral angle of 71.48 (5)¡ã. In the crystal structure, intermolecular O¡ªH...O and C¡ªH...O hydrogen bonds link the molecules into a three-dimensional network. Two weak C¡ªH...¦Ð interactions are also present.
%U http://scripts.iucr.org/cgi-bin/paper?S1600536809030980