%0 Journal Article
%T catena-Poly[[[aqua(1,10-phenanthroline)zinc(II)]-μ-3,3′-(p-phenylene)diacrylato] hemihydrate]
%A Ya-Ping Li
%A Da-Jun Sun
%A Hu Zang
%A Guan-Fang Su
%J Acta Crystallographica Section E
%D 2009
%I International Union of Crystallography
%R 10.1107/s1600536809025665
%X In the title compound, {[Zn(C12H8O4)(C12H8N2)(H2O)]¡¤0.5H2O}n, each ZnII atom is six-coordinated by two N atoms from one 1,10-phenanthroline (phen), three carboxylate O atoms from two different L ligands [H2L = 3,3¡ä-(p-phenylene)diacrylic acid] and one water molecule in a distorted octahedral environment. The two L dianions are situated across inversion centres and bridge neighbouring ZnII centres, yielding a chain propagating parallel to [100]. O¡ªH...O hydrogen bonds between the coordinated water molecule, the solvent water molecule (half-occupied) and the carboxylate O atoms further stabilize the structure.
%U http://scripts.iucr.org/cgi-bin/paper?S1600536809025665