%0 Journal Article
%T cis-Bis[1-allyl-3-(2-pyridyl-κN)thioureato-κS]palladium(II)
%A Svitlana Orysyk
%A Volodimir Bon
%A Vasily Pekhnyo
%J Acta Crystallographica Section E
%D 2009
%I International Union of Crystallography
%R 10.1107/s1600536809029262
%X Yellow plate-like shaped crystals of the title compound, [Pd(C9H10N3S)2], were obtained by ligand-exchange reaction between palladium(II) acetylacetonate and the corresponding organic reagent at room temperature. The PdII atom shows a slightly distorted square-planar coordination geometry consisting of two ligand molecules in a cis conformation that bind in their thiolic tautomeric form. Weak intermolecular Pd...H interactions with Pd¡ªH distances of 3.328 (2)   were observed in the crystal structure. The three-dimensional network of the crystal structure is realized by weak intermolecular C¡ªH...N, N¡ªH...N and C¡ªH...S hydrogen bonds.
%U http://scripts.iucr.org/cgi-bin/paper?S1600536809029262