%0 Journal Article
%T Bis[μ-2-(2-benzoylhydrazinylidenemethyl)-6-methoxyphenolato][2-(2-benzoylhydrazinylidenemethyl)-6-methoxyphenolato]dimanganese(II) perchlorate methanol solvate
%A Gui-Miao Yu
%A Yun-Hui Li
%A Li-Fei Zou
%A Jian-Wei Zhu
%J Acta Crystallographica Section E
%D 2010
%I International Union of Crystallography
%R 10.1107/s1600536810018040
%X In the title complex, [Mn2(C15H13N2O3)3]ClO4¡¤CH3OH, the two MnII ions are bridged by two phenolate O atoms from two ligands, forming an Mn2O2 quadrangle. Each MnII ion has a distorted octahedral coordination geometry. One MnII ion is coordinated by two N atoms and four O atoms from two ligands, and the other is coordinated by one N atom and five O atoms from three ligands. A dimer is formed by intermolecular N¡ªH...O hydrogen bonds. The dimers, perchlorate anions and methanol solvent molecules are further connected into a chain along [overline{1}01] through N¡ªH...O and O¡ªH...O hydrogen bonds.
%U http://scripts.iucr.org/cgi-bin/paper?S1600536810018040